Effect of silica fume substitution by limestone powder and cement kiln dust on the shrinkage, durability, and sustainability of UHPC.

Silica fume is usually used in UHPC, three times more than that for normal concrete, to enhance mechanical properties and durability. However, silica fume (SF) is an expensive material and has high production costs. This work is aimed at investigating the shrinkage and durability performance of previously developed UHPC mixtures utilizing the two calcareous waste materials, namely limestone powder (LSP) and cement kiln dust (CKD), by partially replacing the silica fume. The optimally selected mixtures of UHPC, having flow and strength above the minimum required, were used for detailed investigation in terms of shrinkage and durability characteristics. The results showed that by replacing SF with up to 20% of LSP and up to 20% of CKD, the mechanical properties of UHPC remained satisfactory compared to the control mixture with 100% SF. However, the ultimate shrinkage was higher for mixtures incorporating LSP or CKD, indicating the need for more volume of steel fibers to compensate for the shrinkage strains. The developed UHPCs also exhibited high resistance against reinforcement corrosion and sulfate attack, making them suitable for use in aggressive exposure conditions. However, special attention needs to be paid to the CKD content, where it is recommended to limit the content of CKD to about 15% or less to control the durability performance of the UHPCs. In addition, the sustainability analysis of developed UHPC mixtures was carried out using the life-cycle assessment and eco-strength intensity index. The results indicated that the UHPC mixtures possess a higher life-cycle and are therefore more sustainable.

Tension Stiffening and Cracking Behavior of Axially Loaded Alkali-Activated Concrete.

Alkali-activated concrete is an eco-friendly construction material that is used to preserve natural resources and promote sustainability in the construction industry. This emerging concrete consists of fine and coarse aggregates and fly ash that constitute the binder when mixed with alkaline activators, such as sodium hydroxide (NaOH) and sodium silicate (Na2SiO3). However, understanding its tension stiffening and crack spacing and width is of critical importance in fulfilling serviceability requirements. Therefore, this research aims to evaluate the tension stiffening and cracking performance of alkali-activated (AA) concrete. The variables considered in this study were compressive strength (fc) and concrete cover-to-bar diameter (Cc/db) ratios. After casting the specimen, they were cured before testing at ambient curing conditions for 180 days to reduce the effects of concrete shrinkage and obtain more realistic cracking results. The results showed that both AA and OPC concrete prisms develop slightly similar axial cracking force and corresponding cracking strain, but OPC concrete prisms exhibited a brittle behavior, resulting in a sudden drop in the load-strain curves at the crack location. In contrast, AA concrete prisms developed more than one crack simultaneously, suggesting a more uniform tensile strength compared to OPC specimens. The tension-stiffening factor (ß) of AA concrete exhibited better ductile behavior than OPC concrete due to the strain compatibility between concrete and steel even after crack ignition. It was also observed that increasing the confinement (Cc/db ratio) around the steel bar delays internal crack formation and enhances tension stiffening in AAC. Comparing the experimental crack spacing and width with the values predicted using OPC codes of practice, such as EC2 and ACI 224R, revealed that EC2 tends to underestimate the maximum crack width, while ACI 224R provided better predictions. Thus, models to predict crack spacing and width have been proposed accordingly.

Characterization and Applications of Red Mud, an Aluminum Industry Waste Material, in the Construction and Building Industries, as well as Catalysis.

The disposal of red mud (RM), a waste material generated by the aluminum industry, remains a global environmental concern because of its high alkalinity and smaller particle size, which have the potential to pollute air, soil, and water. Recently, efforts have been made to develop a strategy for reusing industrial byproducts, such as RM, and turning waste into value-added products. The use of RM as (i) a supplementary cementitious material for construction and building materials, such as cement, concrete, bricks, ceramics, and geopolymers, and (ii) a catalyst is discussed in this review. Furthermore, the physical, chemical, mineralogical, structural, and thermal properties of RM, as well as its environmental impact, are also discussed in this review. It is possible to conclude that using RM in catalysis, cement, and construction industries is the most efficient way to recycle this byproduct on a large scale. However, the low cementitious properties of RM can be attributed to a reduction in the fresh and mechanical properties of composites incorporating RM. On the other hand, RM can be used as an efficient active catalyst to synthesize organic molecules and reduce air pollution, which not only makes use of solid waste but also lowers the price of the catalyst. The review provides basic information on the characterization of RM and its suitability in various applications, paving the way for more advanced research on the sustainable disposal of RM waste. Future research perspectives on the utilization of RM are also addressed.

Review on Carbonation Study of Reinforcement Concrete Incorporating with Bacteria as Self-Healing Approach.

This study carried out a comprehensive review to determine the carbonation process that causes the most deterioration and destruction of concrete. The carbonation mechanism involved using carbon dioxide (CO2) to penetrate the concrete pore system into the atmosphere and reduce the alkalinity by decreasing the pH level around the reinforcement and initiation of the corrosion process. The use of bacteria in the concrete was to increase the pH of the concrete by producing urease enzyme. This technique may help to maintain concrete alkalinity in high levels, even when the carbonation process occurs, because the CO2 accelerates to the concrete and then converts directly to calcium carbonate, CaCO3. Consequently, the self-healing of the cracks and the pores occurred as a result of the carbonation process and bacteria enzyme reaction. As a result of these reactions, the concrete steel is protected, and the concrete properties and durability may improve. However, there are several factors that control carbonation which have been grouped into internal and external factors. Many studies on carbonation have been carried out to explore the effect of bacteria to improve durability and concrete strength. However, an in-depth literature review revealed that the use of bacteria as a self-healing mechanism can still be improved upon. This review aimed to highlight and discuss the possibility of applying bacteria in concrete to improve reinforcement concrete.

Effect of Carbon Nanofibers on Physical, Adhesion and Rheological Properties of Liquid Epoxidized Natural Rubber Modified Asphalt.

This study aimed to evaluate the effects of carbon nanofibers (CNFs) on the performance of liquid epoxidized natural rubber (LENR)-modified asphalt. The physical, adhesion and rheological properties were determined by several tests such as penetration, elastic recovery, ring and ball softening point, Brookfield rotational viscometer, AFM and dynamic shear rheometer. LENR was used at concentrations of 3, 6, and 9%, while CNFs were used at contents of 0.3, 0.4, and 0.5% by weight of asphalt. Conventional test results showed that the increases in LENR and LENR/CNFs composite contents in binder leads to an increase in the hardness and consistency and a reduction in the temperature susceptibility of base asphalt. Adhesion results revealed that the addition of CNFs significantly increases the adhesion and bonding properties of base and rubberized binders. Rheological properties analysis exhibited that LENR improved the viscoelastic properties and permanent deformation resistance of asphalt at different temperatures and frequencies. On the other hand, it was found that the addition of CNFs significantly improves the stiffness, elasticity, and hardness of LENR-modified binders. The 6% LENR and 0.4% CNFs were found to be the optimum to enhance the physical, adhesion, and rheological properties of asphalt in this study. Thus, it can be stated that the addition of CNFs is promising to improve the performance of rubberized binders for high temperature applications.

Elucidating the Effects of Reaction Time on the Physicochemical Characterization of Valorized Synthesized Alumina.

Aluminum waste-can management in Malaysia has recently become a serious environmental and public health issue, particularly in metropolitan areas. This has prompted the need to valorize these waste-cans into value-added products using the most economical and environmentally friendly techniques. In this study, the sol-gel technique was used to synthesize high-quality alumina from the aluminum waste-cans collected. From this method, the observed peaks of the synthesized alumina were identified as diaspore (α-AlO(OH)), boehmite (γ-AlO(OH)), aluminum oxide, or gamma-alumina (γ-Al2O3) crystalline structure and corundum. The morphological configuration, microstructure, and functional group properties of the synthesized alumina were evaluated. All the synthesized alumina exhibited a non-spherical shape and appeared to have hexagonal-like shape particles. Moreover, the XRD patterns of the synthesized alumina AL-6-30 and AL-12-30 exhibited a small angle (1-10°) with no XRD peak, which indicated a mesoporous pore structure with no long-range order. The overall results of γ-alumina synthesized from the aluminum waste-cans showed an optimal condition in producing a highly structured γ-alumina with excellent surface-area characteristics. The synthesized alumina exhibited stronger and highly crystalline functional characteristics almost comparable with the commercially available brands on the market.

Mechanical and Durability Performance of Coconut Fiber Reinforced Concrete: A State-of-the-Art Review.

The push for sustainability in the construction sector has demanded the use of increasingly renewable resources. These natural fibers are biodegradable and non-toxic, and their mechanical capabilities are superior to those of synthetic fibers in terms of strength and durability. A lot of research recommends coconut fibers as an alternative to synthetic fibers. However, the knowledge is scattered, and no one can easily judge the suitability of coconut fibers in concrete. This paper presents a summary of research progress on coconut fiber (natural fibers) reinforced concrete. The effects of coconut fibers on the properties of concrete are reviewed. Factors affecting the fresh, hardened, and durability properties of concrete reinforced with coconut fiber are discussed. Results indicate that coconut fiber improved the mechanical performance of concrete due to crack prevention, similar to the synthetic fibers but decreased the flowability of concrete. However, coconut fibers improved flexure strength more effectively than compressive strength. Furthermore, improvement in some durability performance was also observed, but less information is available in this regard. Moreover, the optimum dose is an important parameter for high-strength concrete. The majority of researchers indicate that 3.0% coconut fiber is the optimum dose. The overall study demonstrates that coconut fibers have the creditability to be used in concrete instead of synthetic fibers.

Finite Element Analysis of Rubberized Concrete Interlocking Masonry under Vertical Loading.

Fine aggregate and cement have been partially replaced by 10% and 56% crumb rubber and class F-fly ash, respectively, in order to manufacture rubberized concrete interlocking bricks (RCIBs). The newly developed product has been used for masonry construction without the need for mortar (mortarless), and the experimental testing under compression load was investigated by Al-Fakih et al. Therefore, in line with that, this study carried out finite element (FE) analysis for experimental result validation of masonry walls and prisms made of RCIBs. ANSYS software was utilized to implement the FE analysis, and a plasticity detailed micro-modeling approach was adopted. Parametric studies were carried out on masonry prisms to investigate the effect of the slenderness ratio and the elastic modulus of grout on the prism behavior. The results found that the adopted FE model has the ability to predict the structural response, such as compressive strength, stiffness, and failure mechanism, of the interlocking masonry prisms with about a 90% agreement with the experimental results. Based on the parametric studies, the compressive strength for a 6-course prism is approximately 68% less than a 3-course prism and 60% less than a 5-course prism, which means that the slenderness ratio plays a vital role in the behavior of the RCIB masonry prism under the vertical compression load. Moreover, the results showed that the difference between FE and experimental results of the walls was less than 16%, indicating a good match. The findings also reported that masonry walls and prisms experienced higher ductility measured by the post-failure loading under compression. The finite element model can be used for further investigation of masonry systems built with rubberized concrete interlocking bricks.

Effect of Elevated Temperature on the Compressive Strength and Durability Properties of Crumb Rubber Engineered Cementitious Composite.

This paper reports the findings of the effect of elevated temperature on the compressive strength and durability properties of crumb rubber engineered cementitious composite (CR-ECC). The CR-ECC has been tested for its compressive strength and chemical resistance test against acid and sulphate attack. Different proportions of crumb rubber (CR) in partial replacement to the fine aggregate and polyvinyl alcohol (PVA) fiber have been utilized from 0 to 5% and 0 to 2%. The experiments were designed based on a central composite design (CCD) technique of response surface methodology (RSM). After 28 days curing, the samples were preconditioned and exposed to high temperatures of 100 °C, 200 °C, 300 °C, 400 °C, 500 °C, 600 °C, 700 °C, 800 °C, 900 °C, and 1000 °C for one hour. Although the residual compressive strength of CR-ECC was negatively affected by elevated temperature, no explosive spalling was noticed for all mixes, even at 1000 °C. Results indicated that CR-ECC experiences slight weight gain and a reduction in strength when exposed to the acidic environment. Due to the reduced permeability, CR-ECC experienced less effect when in sulphate environment. The response models were generated and validated by analysis of variance (ANOVA). The difference between adjusted R-squared and predicted R-squared values for each model was less than 0.2, and they possess at least a 95% level of confidence.

Deformation Properties of Rubberized ECC Incorporating Nano Graphene Using Response Surface Methodology.

Engineered cementitious composite (ECC) was discovered as a new substitute of conventional concrete as it provides better results in terms of tensile strain, reaching beyond 3%. From then, more studies were done to partially replace crumb rubber with sand to achieve a more sustainable and eco-friendlier composite from the original ECC. However, the elastic modulus of ECC was noticeably degraded. This could bring potential unseen dangerous consequences as the fatigue might happen at any time without any sign. The replacement of crumb rubber was then found to not only bring a more sustainable and eco-friendlier result but also increase the ductility and the durability of the composite, with lighter specific gravity compared to conventional concrete. This study investigated the effects of crumb rubber (CR) and graphene oxide (GO) toward the deformable properties of rubberized ECC, including the compressive strength, elastic modulus, Poisson's ratio, and drying shrinkage. Central composite design (CCD) was utilized to provide 13 reasonable trial mixtures with the ranging level of CR replacement from 0-30% and that of GO from 0.01-0.08%. The results show that GO increased the strength of the developed GO-RECC. It was also found that the addition of CR and GO to ECC brought a notable improvement in mechanical and deformable properties. The predicted model that was developed using response surface methodology (RSM) shows that the variables (compression strength, elastic modulus, Poisson's ratio, and drying shrinkage) rely on the independent (CR and GO) variables and are highly correlated.

Acid and Sulphate Attacks on a Rubberized Engineered Cementitious Composite Containing Graphene Oxide.

The objective of this research was to determine the durability of an engineered cementitious composite (ECC) incorporating crumb rubber (CR) and graphene oxide (GO) with respect to resistance to acid and sulphate attacks. To obtain the mix designs used for this study, response surface methodology (RSM) was utilized, which yielded the composition of 13 mixes containing two variables (crumb rubber and graphene oxide). The crumb rubber had a percentage range of 0-10%, whereas the graphene oxide was tested in the range of 0.01-0.05% by volume. Three types of laboratory tests were used in this study, namely a compressive test, an acid attack test to study its durability against an acidic environment, and a sulphate attack test to examine the length change while exposed to a sulphate solution. Response surface methodology helped develop predictive responsive models and multiple objectives that aided in the optimization of results obtained from the experiments. Furthermore, a rubberized engineered cementitious composite incorporating graphene oxide yielded better chemical attack results compared to those of a normal rubberized engineered cementitious composite. In conclusion, nano-graphene in the form of graphene oxide has the ability to enhance the properties and overcome the limitations of crumb rubber incorporated into an engineered cementitious composite. The optimal mix was attained with 10% crumb rubber and 0.01 graphene oxide that achieved 43.6 MPa compressive strength, 29.4% weight loss, and 2.19% expansion. The addition of GO enhances the performance of rubberized ECC, contributing to less weight loss due to the deterioration of acidic media on the ECC. It also contributes to better resistance to changes in the length of the rubberized ECC samples.

Flexural Behavior of Double-Skin Steel Tube Beams Filled with Fiber-Reinforced Cementitious Composite and Strengthened with CFRP Sheets.

The concrete-filled double skin steel tube (CFDST) is a more viable option compared to a concrete-filled steel tube (CFST) due to consisting a hollow section, while degradation is enhanced simply by using carbon fiber-reinforced polymer (CFRP). Hence, the stabilization of a concrete's ductile strength needs high- performance fiber-reinforced cementitious conmposite. This study investigates the behavior of high-performance fiber-reinforced cementitious composite-filled double-skin steel tube (HPCFDST) beams strengthened longitudinally with various layers, lengths, and configurtion of CFRP sheets. The findings showed that, with increased CFRP layers, the moment capacity and flexural stiffness values of the retrofitted HPCFDST beams have significantly improved. For an instant, the moment capacity of HPCFDST beams improved by approximately 28.5% and 32.6% when they were wrapped partially along 100% with two and three layers, respectively, compared to the control beam. Moreover, the moment capacity of the HPCFDST beam using two partial layers of CFRP along 75% of its sufficient length was closed to the findings of the beam with two full CFRP layers. For energy absorption, the results showed a vast disparity. Only the two layers with a 100% full length and partial wrapping showed increasing performance over the control. Furthermore, the typical failure mode of HPCFDST beams was observed to be local buckling at the top surface near the point of loading and CFRP rapture at the bottom of effect length.

Strengthening the Structural Behavior of Web Openings in RC Deep Beam Using CFRP.

Deep beams are more susceptible to shear failure, and therefore reparation is a crucial for structural reinforcements. Shear failure is structural concrete failure in nature. It generally occurs without warning; however, it is acceptable for the beam to fail in bending but not in shear. The experimental study presented the structural behavior of the deep beams of reinforced concrete (RC) that reinforces the web openings with externally connected carbon fiber reinforced polymer (CFRP) composite in the shear zone. The structural behavior includes a failure mode, and cracking pattern, load deflection responses, stress concentration and the reinforcement factor were investigated. A total of nine reinforced concrete deep beams with openings strengthened with CFRP and one control beam without an opening have been cast and tested under static four-point bending load till failure. The experimental results showed that the increase the size of the opening causes an increase in the shear strength reduction by up to 30%. Therefore, the larger the openings, the lower the capability of load carriage, in addition to an increase in the number of CFRP layers that could enhance the load carrying capacity. Consequently, utilization of the CFRP layer wrapping technique strengthened the shear behavior of the reinforced concrete deep beams from about 10% to 40%. It was concluded that the most effective number of CFRP layers for the deep beam with opening sizes of 150 mm and 200 mm were two layers and three layers, respectively.

Influence of Secondary Reinforcement on Behaviour of Corbels with Various Types of High-Performance Fiber-Reinforced Cementitious Composites.

An experimental study is conducted to determine the influence of secondary reinforcement on the behaviour of corbels fabricated with three different types of high-performance fiber-reinforced cementitious composites, including engineered cementitious concrete (ECC); high-performance steel fiber-reinforced composite (HPSFRC); and hybrid fiber-reinforced composite (HyFRC). Two shear span-to-depth ratios (a/d = 0.75 and 1.0) are explored. The mechanical properties of the composites in terms of tensile, compressive, and flexural strengths are investigated. Next, the structural behaviour of the high-performance cementitious composite corbels in terms of ultimate load capacity, ductility, and failure modes under the three-point bending test are investigated. The secondary reinforcement is proven to significantly affect stiffness and ultimately load capacity of all three high-performance composite corbels with an aspect ratio of 0.75. However, the secondary reinforcement was more impactful for the HPSFRC corbels, with 51% increase of ultimate strength. Moreover, in terms of damage, fewer cracks occurred in ECC corbels. HPSFRC corbels displayed the highest level of ductility and deformation capacity compared to the other specimens. The results were comparatively analyzed against the predicted results using truss and plastic truss models which provided relatively reliable shear strength.